Precise measurement of phenomenon advances solar cell understanding

Researchers at Washington University in St. Louis have shed light on a basic process that could improve future solar cells. Dewey Holten, Ph.D., professor of chemistry in Arts & Sciences and graduate student Hee-eun Song have directly measured the rate of hole transfer between identical porphyrin compounds in their ground states. These results are key to understanding the fundamental processes underlying charge separation in this sort of structure and have applications for improving the efficiency of solar cells.

Chemists get electrons to ‘break on through to the other side’

David Kilper/WUSTL PhotoChristine Kirmaier (left) and Dewey Holten making adjustments in their sophisticated laser laboratory. Their findings advance the understanding of photosynthesis.In the famous Robert Frost poem, “The Road Not Taken,” the persona, forced to travel one of two roads, takes the one less traveled by, and “that has made all the difference.” Chemists at Washington University in St. Louis and Stanford University, in kinship with Frost, have modified a key protein in a bacterium to move electrons along a pathway not normally traveled by. They got this to happen 70 percent of the time. That yield “makes all the difference.” More…